Open Access
Subscription or Fee Access
A Conductive Polymer Based Electrode in Asymmetric Supercapacitor
Abstract
Most applications and devices in today's smart world rely on electricity to function. In this circumstance, energy storage and energy conservation are critical practices for delivering excellent service. In terms of energy efficiency, rotational stability, and charging and discharging time, supercapacitors exceed batteries. It can withstand a lot more power than standard capacitors
and batteries. In asymmetric designs, this paper looked at how to achieve the high voltage window and high energy storage capacity. Here, porous graphene is deposited on carbon cloth to form a cathode electrode on a supercapacitor, and the carbon cloth (CC) with carbon nanotube (CNT) is polymerized with polyaniline to act as an anode, and the electrochemical performance is
investigated using PVA/ potassium hydroxide as an electrolyte. At a scan rate of 20 mV/s and a current density of 0.8 A/g, the suggested ASC obtained a specific capacitance of 220F/g. The proposed ASC has a 2 V as working voltage window that may be extended at a rate of 20 mV/s. This ASC's key benefit is that it can keep 98 percent of its energy after 5000 cycles. As a result , the
proposed polymer-based anode and porous graphene oxide- based cathode is the optimum choice for constructing Asymmetric supercapacitors.
References
Masikhwa, T. M., Barzegar, F., Dangbegnon, J. K., Bello, A., Madito, M. J., Momodu, D., & Manyala, N. (2016). Asymmetric supercapacitor based on VS 2 nanosheets and activated carbon materials. RSC advances, 6(45), 38990-39000.
Wang, J., Liu, S., Zhang, X., Liu, X., Liu, X., Li, N., ... & Li, Y. (2016). A high energy asymmetric supercapacitor based on flower-like CoMoO4/MnO2 heterostructures and activated carbon. Electrochimica Acta, 213, 663-671.
Vinny, R. T., Chaitra, K., Venkatesh, K., Nagaraju, N., & Kathyayini, N. (2016). An excellent cycle performance of asymmetric supercapacitor based on bristles like α-MnO2 nanoparticles grown on multiwalled carbon nanotubes. Journal of Power Sources, 309, 212-220.
Sennu, P., Aravindan, V., & Lee, Y. S. (2016). High energy asymmetric supercapacitor with 1D@ 2D structured NiCo2O4@ Co3O4 and jackfruit derived high surface area porous carbon. Journal of power sources, 306, 248-257.
Ning, P., Duan, X., Ju, X., Lin, X., Tong, X., Pan, X., ... & Li, Q. (2016). Facile synthesis of carbon nanofibers/MnO2 nanosheets as high-performance electrodes for asymmetric supercapacitors. Electrochimica Acta, 210, 754-761.
Potphode, D. D., Mishra, S. P., Sivaraman, P., & Patri, M. (2017). Asymmetric supercapacitor devices based on dendritic conducting polymer and activated carbon. Electrochimica Acta, 230, 29-38.
Huang, G., Zhang, Y., Wang, L., Sheng, P., & Peng, H. (2017). Fiber-based MnO2/carbon nanotube/polyimide asymmetric supercapacitor. Carbon, 125, 595-604.
Wu, F., Wang, X., Gao, H., Hao, C., & Ge, C. (2017). Synthesis and characterization of hierarchical Bi2MoO6/Polyaniline nanocomposite for all-solid-state asymmetric supercapacitor. Electrochimica Acta, 245, 685-695.
Simotwo, S. K., & Kalra, V. (2018). Polyaniline- carbon based binder-free asymmetric supercapacitor in neutral aqueous electrolyte. Electrochimica Acta, 268, 131-138.
Huang, X., & Gou, L. (2019). High performance asymmetric supercapacitor based on hierarchical flower-like NiCo2S4@ polyaniline. Applied Surface Science, 487, 68-76.
Ge, X., He, Y., Plachy, T., Kazantseva, N., Saha, P., & Cheng, Q. (2019). Hierarchical PANI/NiCo- LDH core-shell composite networks on carbon cloth for high performance asymmetric supercapacitor. Nanomaterials, 9(4), 527.
Sari, F. N. I., & Ting, J. M. (2019). High performance asymmetric supercapacitor having novel 3D networked polypyrrole nanotube/N- doped graphene negative electrode and core- shelled MoO3/PPy supported MoS2 positive electrode. Electrochimica Acta, 320, 134533.
Das, A. K., Paria, S., Maitra, A., Halder, L., Bera, A., Bera, R., ... & Khatua, B. B. (2019). Highly rate capable nanoflower-like NiSe and WO3@ PPy composite electrode materials toward high energy density flexible all-solid-state asymmetric supercapacitor. ACS Applied Electronic Materials, 1(6), 977-990.
Mohd Abdah, M. A. A., Azman, N. H. N., Kulandaivalu, S., & Sulaiman, Y.(2019). Asymmetric supercapacitor of functionalised electrospun carbon fibers/poly(3, 4- ethylenedioxythiophene)/manganese oxide//activated carbon with superior electrochemical performance. Scientific reports, 9(1), 1-9.
Meng, W., Xia, Y., Ma, C., & Du, X. (2020). Electrodeposited polyaniline nanofibers and MoO3 nanobelts for high-performance asymmetric supercapacitor with redox active electrolyte Polymers, 12(10), 2303.
Wang, N., Wang, X., Zhang, Y., Hou, W., Chang, Y., Song, H., ... & Han, G. (2020). All-in-one flexible asymmetric supercapacitor based on composite of polypyrrole-graphene oxide and poly (3, 4-ethylenedioxythiophene). Journal of Alloys and Compounds, 835, 155299.
Azizi, E., Arjomandi, J., Salimi, A., & Lee, J. Y. (2020). Fabrication of an asymmetric supercapacitor based on reduced graphene oxide/polyindole/γ− Al2O3 ternary nanocomposite with high-performance capacitive behavior. Polymer, 195, 122429.
Chhetri, K., Tiwari, A. P., Dahal, B., Ojha, G. P., Mukhiya, T., Lee, M., ... & Kim, H. Y. (2020). A ZIF-8-derived nanoporous carbon nanocomposite wrapped with Co3O4-polyaniline as an efficient electrode material for an asymmetric supercapacitor. Journal of Electroanalytical Chemistry, 856, 113670.
Poudel, M. B., Shin, M., & Kim, H. J. (2021). Polyaniline-silver-manganese dioxide nanorod ternary composite for asymmetric supercapacitor with remarkable electrochemical performance. International Journal of Hydrogen Energy, 46(1), 474-485.
Shah, S. S., Das, H. T., Barai, H. R., & Aziz, M. (2022). Boosting the Electrochemical Performance of Polyaniline by One-Step Electrochemical Deposition on Nickel Foam for High-Performance Asymmetric Supercapacitor. Poly
Refbacks
- There are currently no refbacks.