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Synthesis and Characterization of Poly(vinylpyrrolidone) / Starch / Dimethylacrylamide Hydrogel by Gamma Radiation and Its Application in Basic Fuchsin and Methyl Orange Removal

Nazia Rahman, Puja Majumder, Shahnaz Sultana, Md. Nabul Sardar, Depok Chandra Shil, Md. Ashraful Alam

Abstract


Gamma radiation was used to create a number of PVP/Starch/Dimethylacrylamide (PSD) based hydrogels. Investigated were the effects of several parameters, such as radiation dose, material composition, and pH, on the characteristics of hydrogels, such as gel content and swelling behavior. Radiation doses ranged from 10 to 25 kGy, and 10 kGy was determined to be the ideal dose. Investigations on the impact of dimethylacrylamide (DMA) composition on swelling were investigated. The maximal swelling ratio at 10 kGy for the ideal PVP/starch/DMA composition was 3525%. The ideal composition for hydrogel synthesis consisted of 5% PVP, 0.5% starch, and 5% Dimethylacrylamide, taking into account the gel fraction and swelling ratio. Fourier Transform Infrared-Attenuated Total Reflection (FTIR-ATR) spectroscopy was used to characterize the produced hydrogel. Using basic fuchsin and methyl orange as model dyes, the hydrogel's dye adsorption capability was evaluated using several kinetics and isotherm models. Maximum dye adsorption was 210 mg/g for basic fuchsin (BF) and 473 mg/g for methyl orange (MO), respectively. The Freundlich isotherm model represented the adsorption process better than the Langmuir isotherm model. The adsorption behavior of the PVP/ Starch/ Dimethylacrylamide hydrogel followed pseudo-second order for basic fuchsin (BF) and pseudo-first order for methyl orange (MO). The adsorption process was discovered to be endothermic in nature, spontaneous, and advantageous at high temperature after the thermodynamic parameters were evaluated. Based on the findings, it is expected that PVP/Starch/DMA hydrogel can act as a potential adsorbent to remove cationic and anionic dyes from wastewater.

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